Trichlorosilane, 99%

Code: 175552-100G D2-231

Application

Trichlorosilane has been used to synthesize 11-dicyclohexylphosphino-12-phenyl-9,10-dihydro-9,10-ethenoanthracene (H-KITPHOS) via reduction of 11-dicyclohexylphos...


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Your Price
£75.00 100G
£90.00 inc. VAT

Application

Trichlorosilane has been used to synthesize 11-dicyclohexylphosphino-12-phenyl-9,10-dihydro-9,10-ethenoanthracene (H-KITPHOS) via reduction of 11-dicyclohexylphosphinoyl-12-phenyl-9,10-dihydro-9,10-ethenoanthracene.Other possible applications:Asymmetric reduction of N-aryl ketimines in the presence of a novelL-valine-derived catalyst to form secondary amines.Hydrosilylation of imidazolinones to form chiral imidazolidinones in the presence of a 2,2′-bispyrrolidine based Lewis base organocatalyst.Trichlorosilane activated with chiral N-formylprolinederivatives is an effective reagent for the reduction of imines to formenantiomerically enriched amines.Trichlorosilane reacts with dimethylformamide to form hypervalent hydridosilicates, which can reduce aldehydes to alcohols, imines to amines, and also for the reductive amination of aldehydes.

General description

Trichlorosilane is generally used for the asymmetric hydrosilylation of olefins in the presence of palladium catalysts coordinated with chiral monodentate phosphorus ligands to generate chiral organosilanes.

Packaging

5, 100, 250, 500 g in Sure/Seal™

assay99%
bp32-34 °C (lit.)
density1.342 g/mL at 25 °C (lit.)
expl. lim.70 %
formliquid
InChI keyZDHXKXAHOVTTAH-UHFFFAOYSA-N
InChI1S/Cl3HSi/c1-4(2)3/h4H
Quality Level200
SMILES stringCl[SiH](Cl)Cl
storage temp.2-8°C
vapor density1 (vs air)
vapor pressure9.75 psi ( 20 °C)
Code
Description
Unit Size
List Price
Qty
175552-250G
Unit:250G
List Price: £96.20
Source:List Price
ADD
175552-500G
Unit:500G
List Price: £140.00
Source:List Price
ADD
175552-5G
Unit:5G
List Price: £37.50
Source:List Price
ADD
Cas Number10025-78-2
Hazard Class4.3
Un Number1295
Pack GroupI
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