657697-500mg Display Image

(1R,1R,2S,2S)-DuanPhos,

Code: 657697-500mg D2-231

Application

Chiral Quest Phosphine Ligands for Asymmetric HydrogenationCatalytic ligand used for: Stereoselective synthesis of cyano-substituted dihydropyrroles by annulation...


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Your Price
£542.00 500MG
£650.40 inc. VAT

Application

Chiral Quest Phosphine Ligands for Asymmetric HydrogenationCatalytic ligand used for: Stereoselective synthesis of cyano-substituted dihydropyrroles by annulation of cyanoallenes Rhodium-catalyzed intermolecular enantioselective hydroacylation of alkynes to give alpha- and beta-substituted unsaturated ketones by kinetic resolution Stereoselective preparation of β-amino nitriles via rhodium-catalyzed asymmetric hydrogenation of amino acrylonitriles Stereoselective preparation of anti-1,3-amino alcohols via rhodium-catalyzed asymmetric hydrogenation of β-ketoenamide intermediates Stereoselective preparation of acetylaminoindane via rhodium-catalyzed asymmetric hydrogenation of acetylaminoindene

General description

(1R,1′R,2S,2′S)-DuanPhos is an electron-rich chiral phosphine ligand mainly for transition metal catalyzed asymmetric hydrogenation.

Packaging

100, 500 mg in amber glass bottle

InChI keyHCBRTCFUVLYSKU-SAZLYLDSSA-N
InChI1S/C24H32P2/c1-23(2,3)25-15-17-11-7-9-13-19(17)21(25)22-20-14-10-8-12-18(20)16-26(22)24(4,5)6/h7-14,21-22H,15-16H2,1-6H3/t21-,22-,25-,26-/m1/s1
mp214-246 °C
optical activity[α]20/D +18°, c = 1 in chloroform
Quality Level100
SMILES stringCC(C)(C)P1Cc2ccccc2C1C3P(Cc4ccccc34)C(C)(C)C
Code
Description
Unit Size
List Price
Qty
657697-100MG
Unit:100MG
List Price: £155.00
Source:List Price
ADD
Cas Number528814-26-8
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