2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution, 1.0 M in THF/toluene

Code: 703540-4x25ml D2-231

Application

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functional...


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Application

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.

Selective Deprotonations using Knochel-Hauser-Base

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Product of Albemarle US Inc

Packaging

4×25, 100, 500 mL in Sure/Seal™

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

concentration20 % (w/w), 1.0 M in THF/toluene
density0.96 g/mL at 25 °C
formliquid
InChI keyJHBZAAACZVPPRQ-UHFFFAOYSA-L
InChI1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
Quality Level100
reaction suitabilityreaction type: Grignard Reaction
SMILES string[Li+].[Cl-].CC1(C)CCCC(C)(C)N1[Mg]Cl
storage temp.2-8°C
Code
Description
Unit Size
List Price
Qty
703540-100ML
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution, 1.0 M in THF/toluene

Unit:100ML
List Price: £206.00
Source:List Price
ADD
703540-500ML
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution, 1.0 M in THF/toluene

Unit:500ML
List Price: £574.00
Source:List Price
ADD
Cas Number898838-07-8
Hazard Class4.3
Un Number3399
Pack GroupI
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